Transition State Spectroscopy of the Photoinduced Ca + CH3F Reaction. 1. A Cluster Isolated Chemical Reaction Study
نویسندگان
چکیده
منابع مشابه
Transition state spectroscopy of the photoinduced Ca + CH(3)F reaction. 1. A cluster isolated chemical reaction study.
The "cluster isolated chemical reactions" technique is used to examine the dynamics of the photoinduced reaction producing electronically excited CaF when 1:1 Ca-CH(3)F complexes are deposited at the surface of large argon clusters. This technique ensures quantitatively that 1:1 complexes are actually at the origin of the observed signals. The reaction is monitored by observing the CaF chemilum...
متن کاملTransition state spectroscopy of the photoinduced Ca + CH3F reaction. 2. Experimental and ab initio studies of the free Ca...FCH3 complex.
The Ca* + CH3F --> CaF + CH3 reaction was photoinduced in 1:1 Ca...CH3F complexes formed in a supersonic expansion. The transition state of the reaction was explored by monitoring the electronically excited product, CaF, while scanning the laser that turns on the reaction. Moreover, the electronic structure of the Ca...FCH3 system was studied using ab initio methods by associating a pseudopoten...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry A
سال: 2005
ISSN: 1089-5639,1520-5215
DOI: 10.1021/jp053128h